Structural changes in MII dithione/dithiolato complexes (M = Ni, Pd, Pt) on varying the dithione functionalization

Author:

Espa Davide1234,Pilia Luca12345,Marchiò Luciano678,Attar Salahuddin S.1234,Barsella Alberto91011,Fort Alain91011,Mercuri Maria Laura1234,Serpe Angela1234,Deplano Paola123412

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche

2. Università di Cagliari

3. Unità di Ricerca dell'INSTM

4. I09042 Monserrato-Cagliari, Italy

5. Dipartimento di Ingegneria Meccanica Chimica e dei Materiali

6. Dipartimento di Chimica

7. Università di Parma

8. I43100 Parma, Italy

9. Departement d'Optique ultra-rapide et Nanophotonique

10. IPCMS-CNRS

11. 67034 Strasbourg Cedex 2, France

12. Dipartimento di Fisica

Abstract

Large differences in the crystal structures of the title triads, induced by interactions exchanged by the peripheral fragments of the ligands, have been found and described through the Hirshfeld surface analysis.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference36 articles.

1. Dithiolene Chemistry: Synthesis, Properties, and Applications, in the Series Progress in Inorganic Chemistry, ed. E. I. Steifel and K. D. Karlin, John Wiley & Sons, Hoboken, New Jersey, vol. 52, 2004

2. Square-planar d8 metal mixed-ligand dithiolene complexes as second order nonlinear optical chromophores: Structure/property relationship

3. P. Deplano , M. L.Mercuri, A.Serpe and L.Pilia, chapter 16 in the book The Chemistry of Metal Enolates, ed. J. Zabicky, John Wiley & Sons, Chichester, 2009

4. Syntheses, Charge Distribution, and Molecular Second-Order Nonlinear Optical Properties of Push-Pull Bisdithiolene Nickel Complexes

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