Mixed sandwich thorium complexes incorporating bis(tri-isopropylsilyl)cyclooctatetraenyl and pentamethylcyclopentadienyl ligands: synthesis, structure and reactivity-Reference-Cited by-同舟云学术

Mixed sandwich thorium complexes incorporating bis(tri-isopropylsilyl)cyclooctatetraenyl and pentamethylcyclopentadienyl ligands: synthesis, structure and reactivity

Published:2015 Issue:6 Volume:44 Page:2588-2596
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Button Zoë E.¹²³⁴⁵,Higgins Jessica A.¹²³⁴⁵,Suvova Markéta¹²³⁴⁵,Cloke F. Geoffrey N.¹²³⁴⁵,Roe S. Mark¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. School of Life Sciences

3. University of Sussex

4. Brighton

5. UK

Abstract

The synthesis of thorium complexes of the type Th(COT^TIPS2)Cp*X (X = Cl, I, CH₂Ph, H) and their reactivity towards CO₂, including reductive coupling to form an oxalate complex, are reported.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02362E

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4. Importance of Energy Level Matching for Bonding in Th3+-Am3+ Actinide Metallocene Amidinates, (C5Me5)2[iPrNC(Me)NiPr]An

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