Use of remote acyl groups for stereoselective 1,2-cis-glycosylation with fluorinated glucosazide thiodonors
Author:
Affiliation:
1. Institute of Chemical Process Fundamentals of the CAS
2. 16502 Praha 6
3. Czech Republic
4. University of Chemistry and Technology Prague
5. 16628 Praha 6
6. Institute of Organic Chemistry and Biochemistry of the CAS
7. Praha 6
Abstract
Introducing remote O-acyl protecting groups enabled 1,2-cis stereoselective glycosylation with fluorinated glucosazide glycosyl donors.
Funder
Grantová Agentura České Republiky
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01065K
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3. Nitroglycal Concatenation: A Broadly Applicable and Efficient Approach to the Synthesis of Complex O-Glycans
4. Ring-Opening of Aziridine-2-Carboxamides with Carbohydrate C1-O-Nucleophiles. Stereoselective Preparation of α- and β-O-Glycosyl Serine Conjugates
5. Nickel-Catalyzed Stereoselective Glycosylation with C(2)-N-Substituted Benzylidene d-Glucosamine and Galactosamine Trichloroacetimidates for the Formation of 1,2-cis-2-Amino Glycosides. Applications to the Synthesis of Heparin Disaccharides, GPI Anchor Pseudodisaccharides, and α-GalNAc
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