High-molecular weight bottlebrushes via continuous flow photoiniferter polymerization of macromonomers

Author:

Sivokhin Alexey1ORCID,Orekhov Dmitry1,Kazantsev Oleg1,Otopkova Ksenia1,Sivokhina Olga2,Chesnokov Yuri3ORCID,Smirnov Michael1,Ovchinnikov Alexey1,Makhov Ilya1

Affiliation:

1. Research Laboratory “New Polymeric Materials”, Nizhny Novgorod State Technical University n.a. R.E. Alekseev, 24 Minin Street, 603950 Nizhny Novgorod, Russia

2. V.A. Kargin Research Institute of Chemistry and Technology of Polymers with Pilot Plant, 606000 Dzerzhinsk, Nizhegorodskaya obl., Russia

3. Shubnikov Institute of Crystallography of Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences, Leninskiy prospect, 59, 119333 Moscow, Russia

Abstract

High-molecular weight amphiphilic PEG-based bottlebrushes have been synthesized via continuous flow photoiniferter polymerization of macromonomers using trithiocarbonates as chain transfer agents.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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