Chemical trends of Mn4+ emission in solids-Reference-Cited by-同舟云学术

Chemical trends of Mn4+ emission in solids

Published:2014 Issue:14 Volume:2 Page:2475-2481
ISSN:2050-7526
Container-title:J. Mater. Chem. C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Du M. H.¹²

Affiliation:

1. Materials Science & Technology Division

2. Oak Ridge, USA

Abstract

Calculated Mn⁴⁺ emission energies for various oxides as functions of Mn–O bond length. The experimental values are shown (in red) wherever available. There are three groups of materials: the ones with small O–Mn–O bond angle distortion (black squares), the ones with large O–Mn–O bond angle distortion (blue circles), and phosphates (green triangles). Weak Mn⁴⁺-ligand hybridization as a result of long Mn–O bond lengths and/or large O–Mn–O bond angle distortion generally leads to higher emission energies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/TC/C4TC00031E

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