Edge activation of an inert polymeric carbon nitride matrix with boosted absorption kinetics and near-infrared response for efficient photocatalytic CO2 reduction

Author:

Liu Qiong12345ORCID,Chen Zhongxin5678ORCID,Tao Weijian910114,Zhu Haiming910114,Zhong Linxin1234,Wang Fuxian1213144,Zou Ren1234,Lei Yongqian1213144,Liu Cuibo5678,Peng Xinwen1234ORCID

Affiliation:

1. State Key Laboratory of Pulp and Paper Engineering

2. South China University of Technology

3. Guangzhou 510641

4. China

5. Department of Chemistry and Centre for Advanced 2D Materials (CA2DM)

6. National University of Singapore

7. Singapore 117543

8. Singapore

9. Centre for Chemistry of High-Performance & Novel Materials

10. Department of Chemistry

11. Zhejiang University

12. Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals

13. Guangdong Institute of Analysis

14. Guangzhou 510070

Abstract

The edge-activation of the polymeric carbon nitride matrix by hydroxyethyl groups results in enhanced CO2 absorption capacity and decrease in the CO2 activation energy barrier.

Funder

National Natural Science Foundation of China

State Key Laboratory of Pulp and Paper Engineering

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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