Zeolite synthesis in hydrated silicate ionic liquids-Reference-Cited by-同舟云学术

Zeolite synthesis in hydrated silicate ionic liquids

Published:2015 Issue: Volume:179 Page:437-449
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

van Tendeloo Leen¹²³⁴,Haouas Mohamed⁵⁶⁷⁸,Martens Johan A.¹²³⁴,Kirschhock C. E. A.¹²³⁴,Breynaert Eric¹²³⁴^ORCID,Taulelle Francis¹²³⁴⁵

Affiliation:

1. Centrum voor Oppervlaktechemie en Katalyse

2. KU Leuven

3. Heverlee

4. Belgium

5. Institut Lavoisier de Versailles

6. University of Versailles Saint-Quentin en Yvelines

7. 78035 Versailles Cedex

8. France

Abstract

Hydrated alkali silicate ionic liquids (HSIL) were prepared by hydrolysis of tetraethoxysilane (TEOS) in alkali hydroxide–water mixtures, inducing coacervation and phase separation. The resulting optically clear, homogenous silicate ionic liquid offers exceptional potential for monitoring zeolite crystallisation. This enhanced synthesis route provides access to analysis of speciation, mechanistic details of zeolite formation, and brings organic-template-free zeolite synthesis by design within reach.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/FD/C4FD00234B

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