Lithium-desorption mechanism in LiMn2O4, Li1.33Mn1.67O4, and Li1.6Mn1.6O4 according to precisely controlled acid treatment and density functional theory calculations
Author:
Affiliation:
1. CAS Key Laboratory of Green Process and Engineering
2. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology
3. Institute of Process Engineering
4. Chinese Academy of Sciences
5. Beijing 100190
Abstract
Li8a+ preferred to be replaced by H+ than Li16d+, desorbed Li+ preferred to diffuse out through vacant 8a sites.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/TA/C9TA06080D
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