Two dimensional inorganic electride-promoted electron transfer efficiency in transfer hydrogenation of alkynes and alkenes

Author:

Kim Ye Ji12345,Kim Sun Min1234,Cho Eun Jin6784,Hosono Hideo9101112,Yang Jung Woon1234,Kim Sung Wng12345

Affiliation:

1. Department of Energy Science

2. Sungkyunkwan University

3. Suwon 440-746

4. Korea

5. Center for Integrated Nanostructure Physics

6. Department of Chemistry

7. Chung-Ang University

8. Seoul 156-756

9. Materials and Structure Laboratory

10. Tokyo Institute of Technology

11. Yokohama 226-8503

12. Japan

Abstract

A simple and highly efficient transfer hydrogenation of alkynes and alkenes by using a two-dimensional electride, dicalcium nitride ([Ca2N]+·e), as an electron transfer agent is disclosed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference29 articles.

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2. The Atom Economy—A Search for Synthetic Efficiency

3. Hydrogenation of carbon–carbon multiple bonds: chemo-, regio- and stereo-selectivity

4. M. Hudlicky , Reductions in Organic Chemistry, Wiley-VCH, New York, 1984

5. J. G. de Vries and C. J.Elsevier, The Handbook of Homogenous Hydrogenation, Wiley-VCH, Weinheim, 1984

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