Eu(iii) and Tb(iii) complexes of 6-fold coordinating ligands showing high affinity for the hydrogen carbonate ion: a spectroscopic and thermodynamic study

Author:

Piccinelli Fabio12345ORCID,De Rosa Chiara12345,Melchior Andrea678910ORCID,Faura Georgina678910ORCID,Tolazzi Marilena678910,Bettinelli Marco12345ORCID

Affiliation:

1. Laboratorio Materiali Luminescenti

2. DB

3. Università di Verona

4. and INSTM

5. 37134 Verona

6. Dipartimento Politecnico di Ingegneria e Architettura

7. Laboratorio di Tecnologie Chimiche

8. Università di Udine

9. 33100 Udine

10. Italy

Abstract

The unprecedented affinity of Eu(bpcd)+ and Eu(bQcd)+ towards HCO3 renders these complexes as high-performing systems for the optical assessment of metabolic acidosis.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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