Breathing and oscillating growth of solid-electrolyte-interphase upon electrochemical cycling

Author:

Zhuo Zengqing12345,Lu Peng678,Delacourt Charles910111213ORCID,Qiao Ruimin458,Xu Kang14158,Pan Feng123ORCID,Harris Stephen J.1658,Yang Wanli458ORCID

Affiliation:

1. School of Advanced Materials, Peking University, Shenzhen Graduate School

2. Shenzhen 518055

3. China

4. Advanced Light Source, Lawrence Berkeley National Laboratory

5. Berkeley

6. General Motors Research and Development Center

7. Warren MI 48090

8. USA

9. Laboratoire de Réactivité et de Chimie des Solides

10. CNRS UMR 7314

11. Université de Picardie Jules Verne

12. Amiens

13. France

14. Electrochemistry Branch, Sensor and Electron Devices Directorate Power and Energy Division U.S. Army Research Laboratory

15. Adelphi

16. Materials Science Division, Lawrence Berkeley National Laboratory

Abstract

We report the first direct experimental evidence of the dynamic formation process of the solid-electrolyte-interphase (SEI) on copper electrodes upon electrochemical cycling.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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