A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls-Reference-Cited by-同舟云学术

A site-selective and stereospecific cascade Suzuki–Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls

Published:2021 Issue:32 Volume:57 Page:3909-3912
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Willems Suzanne¹²³⁴,Toupalas Georgios⁵⁶⁷⁸^ORCID,Reisenbauer Julia C.⁵⁶⁷⁸,Morandi Bill¹²³⁴⁵^ORCID

Affiliation:

1. Max-Planck-Institut für Kohlenforschung

2. Kaiser-Wilhelm-Platz 1

3. Mülheim an der Ruhr 45470

4. Germany

5. Laboratorium für Organische Chemie ETH Zürich

6. Vladimir-Prelog-Weg 3

7. HCI

8. Switzerland

Abstract

A cascade Suzuki–Miyaura cross-coupling between two non-symmetrical coupling partners gave rise to 9,10-dihydrophenanthrenes with full site-selectivity. The choice of base was critical to facilitate the challenging coupling of the secondary boronate group.

Funder

Max-Planck-Gesellschaft

Eidgenössische Technische Hochschule Zürich

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC00648G

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