Exploring the effect of axial ligand substitution (X = Br, NCS, CN) on the photodecomposition and electrochemical activity of [MnX(N–C)(CO)3] complexes-Reference-Cited by-同舟云学术

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Exploring the effect of axial ligand substitution (X = Br, NCS, CN) on the photodecomposition and electrochemical activity of [MnX(N–C)(CO)3] complexes

Published:2015 Issue:5 Volume:44 Page:2122-2131
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Agarwal Jay¹²³⁴,Stanton III Charles J.⁵²³⁴,Shaw Travis W.⁵⁶⁷⁴,Vandezande Jonathon E.¹²³⁴,Majetich George F.⁵²³⁴,Bocarsly Andrew B.⁵⁶⁷⁴,Schaefer III Henry F.¹²³⁴

Affiliation:

1. Center for Computational Quantum Chemistry

2. University of Georgia

3. Athens

4. USA

5. Department of Chemistry

6. Princeton University

7. Princeton

Abstract

Four new Mn(i)-NHC compounds are tested for light stability and catalytic efficiency for reducing CO₂ to CO.

Funder

American Chemical Society Petroleum Research Fund

Division of Chemistry

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03079F

Reference86 articles.

1. Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries

2. Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes

3. Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte

4. Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels

5. Tin Oxide Dependence of the CO2 Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts

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