Ammonia-modified Co(ii) sites in zeolites: IR spectroscopy and spin-resolved charge transfer analysis of NO adsorption complexes-Reference-Cited by-同舟云学术

Ammonia-modified Co(ii) sites in zeolites: IR spectroscopy and spin-resolved charge transfer analysis of NO adsorption complexes

Published:2014 Issue:43 Volume:16 Page:24089-24098
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Góra-Marek Kinga¹²³,Stępniewski Adam⁴⁵,Radoń Mariusz¹²³,Broclawik Ewa⁴⁵

Affiliation:

1. Faculty of Chemistry

2. Jagiellonian University in Kraków

3. 30-060 Krakow, Poland

4. Jerzy Haber Institute of Catalysis PAS

5. 30-239 Krakow, Poland

Abstract

IR spectroscopy and quantum chemical modeling (supplemented by the analysis of charge transfer channels between co-adsorbed ammonia and Co(ii)–NO adduct) show that donor NH₃ co-ligands to cobalt cationic centers in zeolites strongly activate the N−O bond.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP03350G

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