Position of substituents directs the electron transfer properties of entatic state complexes: new insights from guanidine-quinoline copper complexes-Reference-Cited by-同舟云学术

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Position of substituents directs the electron transfer properties of entatic state complexes: new insights from guanidine-quinoline copper complexes

Published:2024 Issue:30 Volume:53 Page:12527-12542
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Heck Joshua¹^ORCID,Kucenko Anastasia¹^ORCID,Hoffmann Alexander¹^ORCID,Herres-Pawlis Sonja¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1a, 52074 Aachen, Germany

Abstract

Two novel ligands with a methyl or methyl ester substituent in the 4-position were synthesized. The substituent influence on the properties of the corresponding copper complexes was examined by a plethora of experimental and theoretical methods.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01539H

Reference70 articles.

1. Copper—A“Modern” Bioelement

2. Synthetic models of the active site of catechol oxidase: mechanistic studies

3. R. L.Peterson , S.Kim and K. D.Karlin , in Comprehensive inorganic chemistry II , ed. J. Reedijk and K. R. Poeppelmeier , Elsevier , Amsterdam , 2013 , pp. 149–177

4. Copper Active Sites in Biology

5. Metalloproteins Containing Cytochrome, Iron–Sulfur, or Copper Redox Centers

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