Unexpected chalcogen bonds in tetravalent sulfur compounds-Reference-Cited by-同舟云学术

Unexpected chalcogen bonds in tetravalent sulfur compounds

Published:2019 Issue:21 Volume:21 Page:11313-11319
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Franconetti Antonio¹²³⁴^ORCID,Quiñonero David¹²³⁴^ORCID,Frontera Antonio¹²³⁴^ORCID,Resnati Giuseppe⁵¹⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. Universitat de les Illes Balears

3. 07122 Palma (Baleares)

4. Spain

5. Laboratory of Nanostructured Fluorinated Materials (NFMLab)

6. Materials and Chemical Engineering “Giulio Natta”

7. Politecnico di Milano

8. 20131 Milano

Abstract

Combined CSD analysis and theoretical calculations show the importance of the polarizability in chalcogen bonding interactions. We provide evidence that the Lewis base has a preference in some cases for the σ-hole that is opposite to the more polarizable group instead of the more electron withdrawing one.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP01033E

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