<i>Ab initio</i> investigation of hot electron transfer in CO<sub>2</sub> plasmonic photocatalysis in the presence of hydroxyl adsorbate-Reference-Cited by-同舟云学术

Ab initio investigation of hot electron transfer in CO₂ plasmonic photocatalysis in the presence of hydroxyl adsorbate

Published:2024 Issue:6 Volume:9 Page:1030-1041
ISSN:2055-6756
Container-title:Nanoscale Horizons
language:en
Short-container-title:Nanoscale Horiz.

Author:

Fusco Zelio¹^ORCID,Koenig Dirk²^ORCID,Smith Sean C.²^ORCID,Beck Fiona Jean¹^ORCID

Affiliation:

1. Renewable Fuel Group, School of Engineering, College of Engineering, Computing and Cybernetics, The Australian National University, Canberra, ACT 2601, Australia

2. Integrated Materials Design Lab, The Australian National University, Canberra, ACT 2601, Australia

Abstract

Co-adsorbed hydroxyl species play a significant role in changing the energy landscape of the plasmon-mediated CO2 reaction. These promote CO2 activation and transfer of hot electrons in newly formed hybridized orbitals, thereby improving selectivity.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NH/D4NH00046C

Reference87 articles.

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