Cis–trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets-Reference-Cited by-同舟云学术

Cis–trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets

Published:2016 Issue:6 Volume:7 Page:3632-3639
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Jianfeng¹²³⁴⁵,Jung Julie⁶⁷⁸⁹,Zhang Peng¹²³⁴⁵,Zhang Haixia¹²³⁴⁵,Tang Jinkui¹²³⁴⁵^ORCID,Le Guennic Boris⁶⁷⁸⁹^ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022

5. P. R. China

6. Institut des Sciences Chimiques de Rennes

7. UMR 6226 CNRS-Université de Rennes 1

8. 35042 Rennes Cedex

9. France

Abstract

The rotation of the coordinating plane of the square-antiprismatic environment induces a magnetic relaxation path through higher excited states, offering a new way to modulate the geometries of lanthanides to facilitate magnetic relaxation climbing up to higher energy levels.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04510J

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1. Magnetic bistability in a metal-ion cluster

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