Organophotocatalytic carbo-heterofunctionalization of unactivated olefins with pendant nucleophiles

Author:

Fischer David M.1ORCID,Freis Manuel1ORCID,Amberg Willi M.1ORCID,Lindner Henry1ORCID,Carreira Erick M.1ORCID

Affiliation:

1. Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, 8093 Zurich, Switzerland

Abstract

The difunctionalization of unactivated, terminal olefins through intermolecular addition of α-bromoketones, -esters, and -nitriles followed by formation of 4- to 6-membered heterocycles with pendant nucleophiles is reported.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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