In situ spectroscopic investigation of a Pd local structure over Pd/CeO2 and Pd/MnOx–CeO2 during CO oxidation

Author:

Sasmaz Erdem12345ORCID,Wang Chao12345ORCID,Lance Michael J.6785ORCID,Lauterbach Jochen12345ORCID

Affiliation:

1. Smartstate Center for Strategic Approaches to the Generation of Electricity (SAGE)

2. Department of Chemical Engineering

3. University of South Carolina

4. Columbia

5. USA

6. Materials Science and Technology Division

7. Oak Ridge National Laboratory

8. Oak Ridge

Abstract

In situ X-ray absorption fine structure (XAS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments were performed to elucidate the effect of the Pd local structure on low temperature CO oxidation activity of Pd/CeO2 and Pd/MnOx–CeO2.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference103 articles.

1. Environmental Protection Agency , Federal Register, 2012, vol. 77

2. Environmental Protection Agency , Federal Register, 2014, vol. 79

3. H. S. Gandhi , A. G.Piken, M.Shelef and R. G.Delosh, Laboratory Evaluation of Three-Way Catalysts, SAE Technical Paper 760201, 1976

4. Kinetics of the water–gas shift reaction over nanostructured copper–ceria catalysts

5. A Model for the Temperature-Programmed Reduction of Low and High Surface Area Ceria

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