Retuning the potential of the electrochemical leaf-Reference-Cited by-同舟云学术

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Retuning the potential of the electrochemical leaf

Published:2024 Issue: Volume:252 Page:188-207
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Dolińska Marta M.¹^ORCID,Kirwan Adam J.¹^ORCID,Megarity Clare F.¹^ORCID

Affiliation:

1. School of Chemistry, Manchester Institute of Biotechnology, University of Manchester, 131 Princess Street, Manchester M1 7DN, UK

Abstract

By changing an active site tyrosine in FNR (the enzyme central to the e-Leaf) its exclusivity for NADP(H) swaps to NAD(H). Here, an electrochemical study of this variant reveals that the reduction potential of its active site flavin has been retuned.

Funder

University of Manchester

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/FD/D4FD00020J

Reference46 articles.

1. From Protein Film Electrochemistry to Nanoconfined Enzyme Cascades and the Electrochemical Leaf

2. Transfer of photosynthetic NADP+/NADPH recycling activity to a porous metal oxide for highly specific, electrochemically-driven organic synthesis

3. Electrified Nanoconfined Biocatalysis with Rapid Cofactor Recycling

4. Electrocatalytic Volleyball: Rapid Nanoconfined Nicotinamide Cycling for Organic Synthesis in Electrode Pores

5. A hydrogen fuel cell for rapid, enzyme-catalysed organic synthesis with continuous monitoring

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