Experimental and DFT studies of gadolinium decorated graphene oxide materials for their redox properties and as a corrosion inhibition barrier layer on Mg AZ13 alloy in a 3.5% NaCl environment

Author:

N. Palaniappan123ORCID,Cole Ivan S.4567ORCID,Kuznetsov A.891011ORCID,Thomas K. R. Justin81213143ORCID,K. Balasubramanian1516173ORCID,Manickam Sivakumar1819202122ORCID

Affiliation:

1. School of Chemical Science

2. Central University of Gujarat

3. India

4. Advanced Manufacturing and Fabrication Research and Innovation

5. RMIT University

6. Melbourne

7. Australia

8. Department of Chemistry

9. Universidad Técnica Federico Santa Maria

10. Santiago

11. Chile

12. Organic Materials Laboratory

13. Indian Institute of Technology Roorkee

14. Roorkee 247667

15. Department of Materials Engineering

16. Defence Institute of Advanced Technology (DU)

17. Pune

18. Faculty of Engineering

19. Petroleum and Chemical Engineering

20. Universiti Teknologi Brunei

21. Bandar Seri Begawan Be1410

22. Brunei Darussalam

Abstract

Gadolinium electrostatically interacts with the epoxy group of graphene oxide. Non-bonding electrons of graphene oxide enhance electron transfer between the polarized metal alloy surface and product alloy surface from the corrosive medium.

Funder

Central University of Gujarat

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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