Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin-Reference-Cited by-同舟云学术

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin

Published:2017 Issue:1 Volume:8 Page:108-116
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Pankhurst James R.¹²³⁴,Bell Nicola L.¹²³⁴,Zegke Markus¹²³⁴,Platts Lucy N.¹²³⁴,Lamfsus Carlos Alvarez⁵⁶⁷⁸⁹,Maron Laurent⁵⁶⁷⁸⁹,Natrajan Louise S.¹⁰¹¹¹²¹³⁴,Sproules Stephen¹⁴¹⁵¹⁶⁴,Arnold Polly L.¹²³⁴^ORCID,Love Jason B.¹²³⁴^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh

4. UK

5. LPCNO

6. INSA

7. Université de Toulouse

8. 31077 Toulouse cedex 4

9. France

10. Centre for Radiochemisty Research

11. School of Chemistry

12. The University of Manchester

13. Manchester

14. WestCHEM School of Chemistry

15. University of Glasgow

16. Glasgow

Abstract

The uranyl(vi) complex UO₂Cl(L) of the redox-active diimino-dipyrrin anion, L⁻ is reported and its reactions with inner- and outer-sphere reductants studied.

Funder

Leverhulme Trust

Engineering and Physical Sciences Research Council

University Of Edinburgh

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC02912D

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1. New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands