Reversible crosslinking and fast stress relaxation in dynamic polymer networks via transalkylation using 1,4-diazabicyclo[2.2.2] octane-Reference-Cited by-同舟云学术

Reversible crosslinking and fast stress relaxation in dynamic polymer networks via transalkylation using 1,4-diazabicyclo[2.2.2] octane

Published:2021 Issue:25 Volume:12 Page:3640-3649
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Maassen Eveline E. L.¹²³⁴⁵^ORCID,Heuts Johan P. A.¹²³⁴⁵^ORCID,Sijbesma Rint P.¹²³⁴⁵^ORCID

Affiliation:

1. Supramolecular Polymer Chemistry group

2. Department of Chemical Engineering and Chemistry

3. and Institute for Complex Molecular Systems

4. Eindhoven University of Technology

5. 5600 MB Eindhoven

Abstract

A dynamic covalent network using transalkylation of benzyl-DABCO crosslinkers features fast relaxation with a very strong temperature dependence. The network is de-crosslinked by an excess of DABCO.

Funder

Technische Universiteit Eindhoven

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00292A

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