Catalytic discrimination between formyl groups in regio- and stereoselective intramolecular cross-aldol reactions-Reference-Cited by-同舟云学术

Catalytic discrimination between formyl groups in regio- and stereoselective intramolecular cross-aldol reactions

Published:2016 Issue:6 Volume:7 Page:3791-3797
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Baba Tomonori¹²³⁴,Yamamoto Junya¹²³⁴,Hayashi Kazuhiro¹²³⁴,Sato Makoto⁵⁶⁷⁸⁴,Yamanaka Masahiro⁵⁶⁷⁸⁴,Kawabata Takeo¹²³⁴,Furuta Takumi¹²³⁴

Affiliation:

1. Institute for Chemical Research

2. Kyoto University

3. Uji

4. Japan

5. Department of Chemistry and Research Center for Smart Molecules

6. Faculty of Science

7. Rikkyo University

8. Tokyo 171-8501

Abstract

Catalytic discrimination between inequivalent formyl groups was achieved by virtue of the mild reactivity of an aniline-type acid–base catalyst for the regio-, diastereo-, and enantioselective intramolecular cross-aldol reactions.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Kyoto University

Naito Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04594K

Reference41 articles.

1. Chemoselectivity and the Curious Reactivity Preferences of Functional Groups

2. Catalyst-Controlled Regioselective Reactions of Carbohydrate Derivatives

3. Catalytic Selective Synthesis

4. The Direct Catalytic Asymmetric Cross-Aldol Reaction of Aldehydes

5. The direct catalytic asymmetric aldol reaction

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