A cascade of magnetic phase transitions and a 1/3-magnetization plateau in selenite–selenate Co3(SeO3)(SeO4)(OH)2 with kagomé-like Co2+ ion layer arrangements: the importance of identifying a correct spin lattice-Reference-Cited by-同舟云学术

A cascade of magnetic phase transitions and a 1/3-magnetization plateau in selenite–selenate Co₃(SeO₃)(SeO₄)(OH)₂ with kagomé-like Co²⁺ ion layer arrangements: the importance of identifying a correct spin lattice

Published:2023 Issue:28 Volume:52 Page:9664-9672
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Murtazoev A. F.¹²,Berdonosov P. S.¹²^ORCID,Lyssenko K. A.¹³,Dolgikh V. A.¹,Geidorf M. Y.¹²,Volkova O. S.¹²^ORCID,Koo H.-J.⁴,Whangbo M.-H.⁴⁵,Vasiliev A. N.²^ORCID

Affiliation:

1. Lomonosov Moscow State University, Moscow 119991, Russia

2. National University of Science and Technology “MISiS”, Moscow 119049, Russia

3. Plekhanov Russian University of Economics, Moscow 117997, Russia

4. Department of Chemistry and Research Institute for Basic Sciences, Kyung Hee University, Seoul 02447, Republic of Korea

5. Department of Chemistry, North Carolina State University, Raleigh, NC 27695-8204, USA

Abstract

Co3(SeO3)(SeO4)(OH)2 has kagomé-like layers of Co2+ ions. It undergoes magnetic transitions at 27.5, 19.4 and 8.1 K, and exhibits a 1/3-magnetization plateau. The H–T diagram shows an antiferromagnetic phase I and ferrimagnetic phases II and III.

Funder

Russian Science Foundation

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01620J

Reference41 articles.

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2. Vesignieite BaCu3V2O8(OH)2 as a Candidate Spin-1/2 Kagome Antiferromagnet

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4. Perfect kagome-lattice antiferromagnets with Jeff=12 : The Co2+ analogs of the copper minerals volborthite and vesignieite

5. Spin chirality on a two-dimensional frustrated lattice

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