Synthesis and structure of Pd(<scp>ii</scp>) pincer complexes: catalytic application in β-alkylation of secondary alcohols involving sequential dehydrogenation of alcohols <i>via</i> the borrowing hydrogen approach-Reference-Cited by-同舟云学术

Synthesis and structure of Pd(ii) pincer complexes: catalytic application in β-alkylation of secondary alcohols involving sequential dehydrogenation of alcohols via the borrowing hydrogen approach

Published:2023 Issue:29 Volume:52 Page:10038-10044
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pranesh Kavin Sekar¹,Ramesh Rengan¹^ORCID

Affiliation:

1. Centre for Organometallic Chemistry, School of Chemistry, Bharathidasan University, Tiruchirappalli – 620 024, Tamilnadu, India

Abstract

Pincer Pd(ii) catalyst facilitated β-alkylation of secondary alcohols via the borrowing hydrogen method is reported. The catalytic protocol produces a diverse range of α-branched ketones with an excellent yield of 95% with 0.5 mol% catalyst loading.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01628E

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