Au54(Et3P)18Cl12: a structurally related cluster to Au32(Et3P)12Cl8 gives insight into the formation process-Reference-Cited by-同舟云学术

Au54(Et3P)18Cl12: a structurally related cluster to Au32(Et3P)12Cl8 gives insight into the formation process

Published:2020 Issue:31 Volume:49 Page:10765-10771
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kenzler Sebastian¹²³⁴,Schrenk Claudio¹²³⁴^ORCID,Schnepf Andreas¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Universität Tübingen

3. D-72076 Tübingen

4. Germany

Abstract

Cluster fusion? A slight change in the synthetic procedure of Au₃₂(Et₃P)₁₂Cl₈ leads to the metalloid gold cluster Au₅₄(Et₃P)₁₈Cl₁₂, giving further insight into the formation mechanism, showing new structural motifs within metalloid gold clusters

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02262D

Reference45 articles.

1. Metalloid Aluminum and Gallium Clusters: Element Modifications on the Molecular Scale?

2. A. Schnepf , in Clusters- Contemporary Insight in Structure and Bonding (Hrsg.: J. S. Dehnen), Structure and Bonding , Springer , Berlin , 2017 , vol. 174 , p. 135–200

3. [Al7{N(SiMe3)2}6]−: A First Step towards Aluminum Metal Formation by Disproportionation

4. Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

5. Recent advances in the synthesis and catalytic applications of ligand-protected, atomically precise metal nanoclusters

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Comprehensive and practical guidelines for reduction synthesis of atomically precise coinage–metal nanoclusters;Polyoxometalates;2025-06

2. Au30(PiPr2nBu)12Cl6—An Open Cluster Provides Insight into the Influence of the Sterical Demand of the Phosphine Ligand in the Formation of Metalloid Gold Clusters;Molecules;2024-01-05

3. Two triplet emitting states in one emitter: Near-infrared dual-phosphorescent Au ₂₀ nanocluster;Science Advances;2023-03-31

4. Appendix;Atomically Precise Metal Nanoclusters;2023

5. A Review of State of the Art in Phosphine Ligated Gold Clusters and Application in Catalysis;Advanced Science;2022-03-25