Dynamics of structural diffusion in phosphoric acid hydrogen-bond clusters
Author:
Affiliation:
1. School of Chemistry
2. Institute of Science
3. Suranaree University of Technology
4. Nakhon Ratchasima 30000
5. Thailand
Abstract
For protonated H3PO4 clusters, the Eigen–Zundel–Eigen mechanism is enhanced by fluctuations in the H-bond chain length and local-dielectric environment, and can proceed without the reorientation of H3PO4 molecules as in the case of neat liquid H3PO4.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA01829K
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