Decanuclear FeIII clusters with hemiacetal ligands: a new {M10(μ3-O)8} cluster core-Reference-Cited by-同舟云学术

Decanuclear FeIII clusters with hemiacetal ligands: a new {M10(μ3-O)8} cluster core

Published:2019 Issue:35 Volume:48 Page:13139-13142
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mayans J.¹²³⁴⁵,Roc L.¹²³⁴⁵,Font-Bardia M.⁶⁷³⁸⁵,Escuer A.¹²³⁴⁵^ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica

2. Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotecnology

3. Universitat de Barcelona

4. Barcelona-08028

5. Spain

6. Departament de Mineralogia

7. Cristal·lografia i Dipòsits Minerals and Unitat de Difracció de R-X. Centre Científic i Tecnològic de la Universitat de Barcelona (CCiTUB)

8. 08028 Barcelona

Abstract

The characterization of a Fe^III₁₀ cluster with α-methyl-2-pyridinemethanolate lead us to explore the direct syntheses of medium nuclearity Fe^III clusters with aldehydes in methanol. The complexes exhibit an unprecedented {Fe₁₀(μ₃-O)₈} cluster core.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01568J

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