Programmable synthesis of organic cages with reduced symmetry-Reference-Cited by-同舟云学术

Programmable synthesis of organic cages with reduced symmetry

Published:2024 Issue:17 Volume:15 Page:6536-6543
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Andrews Keith G.¹²^ORCID,Horton Peter N.³^ORCID,Coles Simon J.³^ORCID

Affiliation:

1. Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Oxford OX1 3TA, UK

2. Department of Chemistry, Durham University, Lower Mount Joy, South Rd, Durham, DH1 3LE, UK

3. UK National Crystallography Service, School of Chemistry, Faculty of Engineering and Physical Sciences, University of Southampton, Southampton, SO17 1BJ, UK

Abstract

The rules underpinning the dynamic low-symmetry conformation of a symmetric organic cage are decoded, and rationally reapplied to access new cages with constrained symmetry. This allows tuning of conformation, height and shape for guest binding.

Funder

Linacre College, University of Oxford

Royal Commission for the Exhibition of 1851

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00889H

Reference90 articles.

1. Supramolecular catalysis. Part 2: artificial enzyme mimics

2. Making more with less: confinement effects for more sustainable chemical transformations

3. Molecular Behavior in Small Spaces

4. Triazine-based covalent organic polymers: design, synthesis and applications in heterogeneous catalysis

5. Reactivity in Confined Spaces , ed. G. Lloyd ; and R. S. Forgan , The Royal Society of Chemistry , 2021

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