A simple access to transition metal cyclopropenylidene complexes

Author:

Bidal Yannick D.1234,Lesieur Mathieu1234,Melaimi Mohand56789,Cordes David B.1234,Slawin Alexandra M. Z.1234,Bertrand Guy56789,Cazin Catherine S. J.1234

Affiliation:

1. EaStCHEM School of Chemistry

2. University of St. Andrews

3. St. Andrews

4. UK

5. UCSD-CNRS Joint Research Laboratory (UMI 3555)

6. Department of Chemistry and Biochemistry

7. University of California

8. San Diego

9. La Jolla

Abstract

The first example of a BAC–Cu complex, its outstanding catalytic activity in Click chemistry and its use as a carbene-transfer reagent to easily access Au-, Pd–, Ir– and Rh–BAC compounds are reported.

Funder

Royal Society

Advanced Research Projects Agency - Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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