Electronic effects on the mechanism of the NAD<sup>+</sup> coenzyme reduction catalysed by a non-organometallic ruthenium(<scp>ii</scp>) polypyridyl amine complex in the presence of formate-Reference-Cited by-同舟云学术

Electronic effects on the mechanism of the NAD⁺ coenzyme reduction catalysed by a non-organometallic ruthenium(ii) polypyridyl amine complex in the presence of formate

Published:2022 Issue:33 Volume:12 Page:21191-21202
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Chrzanowska Marta¹^ORCID,Katafias Anna¹^ORCID,van Eldik Rudi¹²^ORCID,Conradie Jeanet³⁴^ORCID

Affiliation:

1. Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland

2. Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Egerlandstr. 1, 91058 Erlangen, Germany

3. Faculty of Natural and Agricultural Sciences, University of the Free State, Bloemfontein 9300, Republic of South Africa

4. Department of Chemistry, UiT – The Arctic University of Norway, N-9037 Tromsø, Norway

Abstract

The graphical abstract represents the overall catalytic cycle in which the non-organometallic Ru(ii) formato complex releases CO2 and transfers hydride to NAD+ to form NADH coenzyme.

Funder

Narodowe Centrum Nauki

National Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA01890J

Reference44 articles.

1. Reductive Stress in Inflammation-Associated Diseases and the Pro-Oxidant Effect of Antioxidant Agents

2. The NAD+/NADH Redox Couple—Insights from the Perspective of Electrochemical Energy Transformation and Biomimetic Chemistry

3. NAD(H) and NADP(H) Redox Couples and Cellular Energy Metabolism

4. Redox Paradox: A Novel Approach to Therapeutics-Resistant Cancer

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