Efficient nickel-catalyzed phosphinylation of C–S bonds forming C–P bonds-Reference-Cited by-同舟云学术

Efficient nickel-catalyzed phosphinylation of C–S bonds forming C–P bonds

Published:2016 Issue:82 Volume:52 Page:12233-12236
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yang Jia¹²³⁴⁵,Xiao Jing¹²³⁴⁵,Chen Tieqiao¹²³⁴⁵,Yin Shuang-Feng¹²³⁴⁵,Han Li-Biao⁶⁷⁸

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics

2. College of Chemistry and Chemical Engineering

3. Hunan University

4. Changsha 410082

5. China

6. National Institute of Advanced Industrial Science and Technology (AIST)

7. Tsukuba

8. Japan

Abstract

The first nickel-catalyzed phosphinylation of C–S bonds forming C–P bonds is developed. The reaction can proceed readily with the simple Ni(cod)₂ at a loading down to 0.1 mol% at the 10 mmol scale. Various aryl sulfur compounds, i.e. sulfides, sulfoxides and sulfones all couple with P(O)–H compounds to produce the corresponding organophosphorus compounds, which provides an efficient new method for the construction of C–P bonds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC06048J

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3. Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

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5. Catalytic Transformations Involving the Activation of sp2 Carbon–Oxygen Bonds

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