Cu-ATC vs. Cu-BTC: comparing the H2 adsorption mechanism through experiment, molecular simulation, and inelastic neutron scattering studies

Author:

Pham Tony1ORCID,Forrest Katherine A.1,Niu Zheng2,Tudor Brant1,Starkey Chloe B.1,Wang Yue2,Eddaoudi Mohamed3ORCID,Rosi Nathaniel4ORCID,Orcajo Gisela5,Eckert Juergen16ORCID,Ma Shengqian7ORCID,Space Brian18ORCID

Affiliation:

1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, Florida 33620-5250, USA

2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, People's Republic of China

3. Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia

4. Department of Chemistry, University of Pittsburgh, Chevron Science Center, 219 Parkman Avenue, Pittsburgh, Pennsylvania 15260, USA

5. Department of Chemical and Energy Technology, ESCET, Rey Juan Carlos University, C/Tulipán s/n, 28933 Móstoles, Madrid, Spain

6. Department of Chemistry and Biochemistry, Texas Tech University, 2500 Broadway, Box 41061, Lubbock, Texas 79409-1061, USA

7. Department of Chemistry, University of North Texas, 1508 West Mulberry Street, Denton, Texas 76201, USA

8. Department of Chemistry, North Carolina State University, 2700 Stinson Drive, Cox Hall 506, Raleigh, North Carolina 27607, USA

Abstract

A combined experimental, inelastic neutron scattering, and theoretical study revealed that the metal–organic framework Cu-ATC exhibits greater H2 adsorption affinity compared to the well-known Cu-BTC.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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