Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization
Author:
Affiliation:
1. Department of Chemistry
2. M. V. Lomonosov Moscow State University
3. Moscow 119991
4. Russian Federation
5. Baytown Technology and Engineering Complex
6. ExxonMobil Chemical Company
7. Baytown
8. USA
Abstract
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
Funder
Exxon Mobil Corporation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01031F
Reference21 articles.
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3. A Fully Integrated High-Throughput Screening Methodology for the Discovery of New Polyolefin Catalysts: Discovery of a New Class of High Temperature Single-Site Group (IV) Copolymerization Catalysts
4. Nonconventional Catalysts for Isotactic Propene Polymerization in Solution Developed by Using High-Throughput-Screening Technologies
5. Pyridylamido Hafnium and Zirconium Complexes: Synthesis, Dynamic Behavior, and Ethylene/1-Octene and Propylene Polymerization Reactions
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