On-surface cyclodehydrogenation reaction pathway determined by selective molecular deuterations-Reference-Cited by-同舟云学术

On-surface cyclodehydrogenation reaction pathway determined by selective molecular deuterations

Published:2021 Issue:47 Volume:12 Page:15637-15644
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ma Chuanxu¹²^ORCID,Xiao Zhongcan³^ORCID,Bonnesen Peter V.¹,Liang Liangbo¹^ORCID,Puretzky Alexander A.¹,Huang Jingsong¹^ORCID,Kolmer Marek¹⁴,Sumpter Bobby G.¹^ORCID,Lu Wenchang³⁵,Hong Kunlun¹,Bernholc Jerzy³⁵^ORCID,Li An-Ping¹^ORCID

Affiliation:

1. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

2. Hefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026, China

3. Department of Physics, North Carolina State University, Raleigh, NC 27695, USA

4. Ames Laboratory, U.S. Department of Energy, Ames, IA 50011, USA

5. Computational Sciences and Engineering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

Abstract

Selective deuterations were exploited to synthesize graphene nanoribbons on Au(111) surface with a specific H/D pattern on edges, allowing the determination of cyclodehydrogenation reaction pathway within the framework of pericyclic reactions.

Funder

National Natural Science Foundation of China

Office of Naval Research

Chinese Academy of Sciences

National Centre for Supercomputing Applications

Office of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04908A