Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes-Reference-Cited by-同舟云学术

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Published:2024 Issue:34 Volume:53 Page:14212-14218
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jurt Pascal¹,Gamboa-Carballo Juan José¹²^ORCID,Schweinzer Clara¹^ORCID,Himmelbauer Daniel³^ORCID,Thöny Debora¹^ORCID,Gianetti Thomas L.⁴,Trincado Monica¹⁵^ORCID,Grützmacher Hansjörg¹^ORCID

Affiliation:

1. Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland

2. Higher Institute of Technologies and Applied Sciences (InSTEC), University of Havana, Ave. S. Allende 1110, 10600 Havana, Cuba

3. Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, A-1060 Vienna, Austria

4. Department of Chemistry and Biochemistry, University of Arizona, University Blvd., Tucson, AZ 85719, USA

5. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland

Abstract

Selective and efficient ammonia borane dehydrogenation is catalysed by an asymmetric bimetallic rhodium complex leading to borazine. The method is extended to the preparation of BNC polymers. A ligand cooperativity mechanism is suggested based on DFT.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Eidgenössische Technische Hochschule Zürich

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01520G

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