B(C6F5)3-catalyzed metal-free hydrogenation of 2-oxazolones-Reference-Cited by-同舟云学术

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B(C₆F₅)₃-catalyzed metal-free hydrogenation of 2-oxazolones

Published:2023 Issue:3 Volume:21 Page:499-502
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Cui Guangyu¹²,Feng Xiangqing¹²^ORCID,Du Haifeng¹²^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The first metal-free hydrogenation of 2-oxazolones was realized to afford a variety of 2-oxazolidinones in 70–98% yields, in which an enamine to imine isomerization was involved.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB01950G

Reference50 articles.

1. 1,2-Amino Alcohols and Their Heterocyclic Derivatives as Chiral Auxiliaries in Asymmetric Synthesis

2. J.Seyden-Penne , Chiral Auxiliaries and Ligands in Asymmetric Synthesis , Wiley , New York , 1995

3. I.Ojima , Catalytic Asymmetric Synthesis , Wiley , New York , 3rd edn, 2010

4. 2-Oxazolidones

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