Rational design of anti-Kasha photoemission from a biazulene core embedded in an antiaromatic/aromatic hybrid

Author:

Diaz-Andres Aitor1ORCID,Marín-Beloqui Jose2ORCID,Wang Junting3,Liu Junzhi3ORCID,Casado Juan2ORCID,Casanova David14ORCID

Affiliation:

1. Donostia International Physics Center (DIPC), 20018 Donostia, Euskadi, Spain

2. Department of Physical Chemistry, University of Malaga, Campus de Teatinos s/n, 29071 Malaga, Spain

3. Department of Chemistry, State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China

4. IKERBASQUE – Basque Foundation for Science, 48009 Bilbao, Euskadi, Spain

Abstract

Design of anti-Kasha emitters based on theJ-coupling of azulenes and molecular rigidity imposed by antiaromatic/aromatic embedding.

Funder

Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía

Agencia Estatal de Investigación

National Natural Science Foundation of China

Eusko Jaurlaritza

Research Grants Council, University Grants Committee

University of Hong Kong

Innovation and Technology Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference51 articles.

1. Molecular Electronic Spectroscopy

2. P.Klán and J.Wirz , Photochemistry of Organic Compounds: From Concepts to Practice , Wiley , 2009

3. N. J.Turro , V.Ramamurthy , V.Ramamurthy and J. C.Scaiano , Principles of Molecular Photochemistry: An Introduction , University Science Books , 2009

4. Characterization of electronic transitions in complex molecules

5. Anomalous Light Emission of Azulene

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