Chromium complexes bearing amidinato-phosphino ligand: synthesis, characterization, and catalytic properties of ethylene tri-/tetramerization and polymerization-Reference-Cited by-同舟云学术

Chromium complexes bearing amidinato-phosphino ligand: synthesis, characterization, and catalytic properties of ethylene tri-/tetramerization and polymerization

Published:2016 Issue:42 Volume:45 Page:17020-17029
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Rui¹²³⁴⁵,Zhu Kongtao¹²³⁴⁵,Zhong Xianghong⁶⁷⁸⁹,Li Jiancheng¹²³⁴⁵,Liu Zhenyu⁶⁷⁸⁹,Chen Shibing⁶⁷⁸⁹,Zhu Hongping¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces

2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters

3. College of Chemistry and Chemical Engineering

4. Xiamen University

5. Xiamen

6. Maoming Branch R&D Institute

7. SINOPEC

8. Maoming 525011

9. China

Abstract

While the N,P-chelation Cr(iii) complex/MAO catalyzes ethylene tri-/tetramerization along with polymerization, the N,N,P-chelation Cr(iii) (or Cr(ii)) complex/MAO enables only polymerization.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03216H

Reference74 articles.

1. High activity ethylene trimerisation catalysts based on diphosphine ligandsElectronic supplementary information (ESI) available: experimental details for catalyst screening runs, together with a typical gas uptake profile. See http://www.rsc.org/suppdata/cc/b2/b201335e/

2. Ethylene Tetramerization: A New Route to Produce 1-Octene in Exceptionally High Selectivities

3. Highly selective chromium-based ethylene trimerisation catalysts with bulky diphosphinoamine ligands

4. Ethylene trimerisation and tetramerisation catalysts with polar-substituted diphosphinoamine ligands

5. Nitrogen-Linked Diphosphine Ligands with Ethers Attached to Nitrogen for Chromium-Catalyzed Ethylene Tri- and Tetramerizations

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