Supramolecular multi-electron redox photosensitisers comprising a ring-shaped Re(<scp>i</scp>) tetranuclear complex and a polyoxometalate-Reference-Cited by-同舟云学术

Supramolecular multi-electron redox photosensitisers comprising a ring-shaped Re(i) tetranuclear complex and a polyoxometalate

Published:2023 Issue:3 Volume:14 Page:691-704
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Takahashi Maria¹,Asatani Tsuyoshi¹,Morimoto Tatsuki²,Kamakura Yoshinobu¹^ORCID,Fujii Kotaro¹^ORCID,Yashima Masatomo¹^ORCID,Hosokawa Naoki¹,Tamaki Yusuke¹,Ishitani Osamu¹³^ORCID

Affiliation:

1. Department of Chemistry, School of Science, Tokyo Institute of Technology, O-okayama 2-12-1-NE-1, Meguro-ku, Tokyo 152-8550, Japan

2. School of Engineering, Tokyo University of Technology, 1404-1 Katakura, Hachioji, Tokyo 192-0982, Japan

3. Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739 8526, Japan

Abstract

Supramolecular photosensitisers comprising a ring-shaped Re(i) tetranuclear complex and a Keggin-type heteropolyoxometalate were synthesised. They can photochemically accumulate four electrons and supply them for the photocatalytic CO2 reduction.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC04252E

Reference54 articles.

1. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

2. Photoredox Catalysis in Organic Chemistry

3. Switchable Divergent Synthesis Using Photocatalysis

4. Photophysical Properties and Redox Potentials of Photosensitizers for Organic Photoredox Transformations

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