A 2,2′-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenes via reversible C–P bond formation-Reference-Cited by-同舟云学术

A 2,2′-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenes via reversible C–P bond formation

Published:2021 Issue:10 Volume:12 Page:3693-3701
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wagner Hannah K.¹²³⁴,Wadepohl Hubert¹²³⁴,Ballmann Joachim¹²³⁴^ORCID

Affiliation:

1. Anorganisch-Chemisches Institut

2. Universität Heidelberg

3. D-69120 Heidelberg

4. Germany

Abstract

A metal-templated synthesis of cyclic (aryl)(ylidic)mesoionic carbene complexes (CArY-MICs) is presented. In the case of molybdenum carbonyls, the crucial P–C bond formation, which occurs during CArY-MIC formation, was found to be reversible.

Funder

Deutsche Forschungsgemeinschaft

Baden-Württemberg Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06128J

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