Hydroboration of internal alkynes catalyzed by FeH(CO)(NO)(PPh3)2: a case of boron-source controlled regioselectivity-Reference-Cited by-同舟云学术

Hydroboration of internal alkynes catalyzed by FeH(CO)(NO)(PPh3)2: a case of boron-source controlled regioselectivity

Published:2020 Issue:5 Volume:10 Page:1492-1497
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Rami Fabian¹²³⁴,Bächtle Franziska¹²³⁴,Plietker Bernd¹²³⁴^ORCID

Affiliation:

1. Institut für Organische Chemie

2. Universität Stuttgart

3. DE-70569 Stuttgart

4. Germany

Abstract

The Fe–H complex FeH(CO)(NO)(Ph₃P)₂ catalyzes the stereoselective, regiodivergent hydroboration of internal alkynes using either pinacolborane (HBpin) or bis(pinacolato)diboron (B₂pin₂) as a boron source.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/C9CY02461A

Reference51 articles.

1. D. G. Hall , in Boronic Acids , ed. D. G. Hall , Wiley-VCH , Weinheim , 2005 , pp. 1–99

2. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

3. Catalytic Hydroboration with Rhodium Complexes

4. Hydroboration of Alkynes with Pinacolborane Catalyzed by HZrCp2Cl

5. A study of hydroboration of alkenes and alkynes with pinacolborane catalyzed by transition metals

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