Configuration and stability of naturally occurring all-cis-tetrahydrofuran lignans from Piper solmsianum

Author:

Ramos Clécio S.1234,Linnert Harrald V.5674,de Moraes Marcilio M.5674,do Amaral João H.5674,Yamaguchi Lydia F.5674,Kato Massuo J.5674ORCID

Affiliation:

1. Department of Chemistry

2. Rural Federal University of Pernambuco

3. 52.171-030 Recife

4. Brazil

5. Institute of Chemistry

6. University of São Paulo

7. 05508-000 São Paulo

Abstract

First occurrence of all-cishexamethoxy-tetrahydrofuran lignans1aand1b, which are 6.5 kcal mol−1less stable than the all-transisomer grandisin (2a).

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Universidade de São Paulo

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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