A new subclass of copper(<scp>i</scp>) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect-Reference-Cited by-同舟云学术

A new subclass of copper(i) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect

Published:2023 Issue:20 Volume:59 Page:2923-2926
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Baranov Andrey Yu.¹,Rakhmanova Mariana I.¹,Hei Xiuze²,Samsonenko Denis G.¹^ORCID,Stass Dmitri V.³⁴,Bagryanskaya Irina Yu.⁵,Ryzhikov Maxim R.¹^ORCID,Fedin Vladimir P.¹,Li Jing²^ORCID,Artem'ev Alexander V.¹^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., Novosibirsk 630090, Russia

2. Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey 08854, USA

3. Voevodsky Institute of Chemical Kinetics and Combustion SB RAS, 3 Institutskaya St., Novosibirsk 630090, Russia

4. Department of Physics, Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090, Russia

5. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Acad. Lavrentiev Ave., Novosibirsk 630090, Russia

Abstract

We present a unique new subclass of Cu(i) hybrid complexes, showing TADF with near-unity quantum yields as well as unprecedented solvatochromic emission and strong X-ray radioluminescence.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00119A

Reference23 articles.

1. Copper Iodide Based Hybrid Phosphors for Energy‐Efficient General Lighting Technologies

2. TADF: Enabling luminescent copper(i) coordination compounds for light-emitting electrochemical cells

3. Recent advances in copper complexes for electrical/light energy conversion

4. Photochemistry and Photophysics of Coordination Compounds: Copper

5. Highly Efficient OLEDs: Materials Based on Thermally Activated Delayed Fluorescence , ed. H. Yersin , Wiley-VCH , Weinheim, Germany , 2019

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