Base-mediated C–B bond activation of benzylic boronate for the rapid construction of β-silyl/boryl functionalized 1,1-diarylalkanes from aromatic alkenes-Reference-Cited by-同舟云学术

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Base-mediated C–B bond activation of benzylic boronate for the rapid construction of β-silyl/boryl functionalized 1,1-diarylalkanes from aromatic alkenes

Published:2023 Issue:42 Volume:14 Page:11881-11889
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gao Liuzhou¹²,Liang Xinyi¹,He Linke¹,Li Guoao¹,Chen Shengda¹,Cao Jia¹,Ma Jing¹^ORCID,Wang Guoqiang¹^ORCID,Li Shuhua¹^ORCID

Affiliation:

1. Institute of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

2. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

Abstract

By shifting the chemical equilibrium of the benzylic boronate–base complex to the free carbanion state, we developed a general, practical, and simple method for the construction of β-silyl/boryl functionalized 1,1-diarylalkanes.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03666A

Reference71 articles.

1. D. G.Hall , Boronic Acids: Preparation and Applications in Organic Synthesis Medicine and Materials , Wiley-VCH : Weinheim , 2nd edn, 2011

2. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds

3. Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)

4. Selection of boron reagents for Suzuki–Miyaura coupling

5. C−H Activation for the Construction of C−B Bonds

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