Catalytic cracking of CH<sub>3</sub>Cl on copper-based phases-Reference-Cited by-同舟云学术

Catalytic cracking of CH₃Cl on copper-based phases

Published:2022 Issue:6 Volume:12 Page:2006-2014
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Blaser Eugénie¹^ORCID,Rosier Cécile²,Huet Michel²,Geantet Christophe¹^ORCID,Loridant Stéphane¹^ORCID

Affiliation:

1. Univ Lyon, Université Claude Bernard-Lyon 1, CNRS, IRCELYON-UMR 5256, 2 Av. A. Einstein, F-69626 Villeurbanne Cedex, France

2. Elkem Silicones France, 9 rue Specia, 69190 Saint Fons, France

Abstract

CuCl and Cu are active phases for CH3Cl cracking, a side reaction of the methylchlorosilanes direct synthesis. In the presence of black carbon simulating coke, CuCl is reduced leading to Cu, inactive for the direct synthesis, and chlorinated coke.

Funder

Association Nationale de la Recherche et de la Technologie

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02226A

Reference24 articles.

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4. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

5. Recent Advances in Rochow‐Müller Process Research: Driving to Molecular Catalysis and to A More Sustainable Silicone Industry

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