Efficient electrocatalytic reduction of carbon dioxide by metal-doped β12-borophene monolayers

Author:

Liu Jin-Hang12345,Yang Li-Ming12345ORCID,Ganz Eric6789ORCID

Affiliation:

1. Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica

2. Key Laboratory of Material Chemistry for Energy Conversion and Storage

3. Ministry of Education

4. Hubei Key Laboratory of Materials Chemistry and Service Failure

5. School of Chemistry and Chemical Engineering

6. School of Physics and Astronomy

7. University of Minnesota

8. Minneapolis

9. USA

Abstract

These new TM–Bβ12 monolayers will display excellent catalytic performance for electroreduction of CO2. Primary reduction product of Sc is CO (overpotential 0.45 V). Primary product Ti–Zn is CH4, and Fe–Bβ12 has 0.45 V overpotential.

Funder

National Natural Science Foundation of China

Huazhong University of Science and Technology

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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