Catalyst-free room-temperature iClick reaction of molybdenum(ii) and tungsten(ii) azide complexes with electron-poor alkynes: structural preferences and kinetic studies
Author:
Affiliation:
1. Institut für Anorganische Chemie
2. Julius-Maximilians-Universität Würzburg
3. D-97074 Würzburg
4. Germany
5. School of Pharmacy
Abstract
The azide complexes [M(η3-allyl)(N3)(bpy)(CO)2] with M = Mo, W smoothly react in a [3 + 2] cycloaddition reaction with electron-poor alkynes.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03096G
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1. Click Chemistry: Diverse Chemical Function from a Few Good Reactions
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